Multifunctionality of silver closo-boranes
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چکیده
منابع مشابه
Multifunctionality of silver closo-boranes
Silver compounds share a rich history in technical applications including photography, catalysis, photocatalysis, cloud seeding and as antimicrobial agents. Here we present a class of silver compounds (Ag2B10H10 and Ag2B12H12) that are semiconductors with a bandgap at 2.3 eV in the green visible light spectrum. The silver boranes have extremely high ion conductivity and dynamic-anion facilitate...
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The symmetry constrained geometries of the eight- and nine-vertex polyhedral boranes and haloboranes BnXnz (n = 8 and 9; X = H, F and Cl; z = -2, -1 and 0) were optimized at the B3LYP/6-311+G(d) level and their nucleus-independent chemical shifts (NICS) were calculated using the GIAO method with Kohn-Sham orbitals. Substitution of halogens on borane cages was found to significantly impact not o...
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The closo-boranes B(x)H(x) (+2), or their corresponding anions [B(x)H(x)](2-) (where x = 5 through 12) and polycycloalkanes C(n)H(n) (where n represents even numbers from 6 through 20) exhibit a complementary relationship whereby the structures of the corresponding molecules, e.g., [B(6)H(6)](2-) and C(8)H(8) (cubane), are based on reciprocal polyhedra. The vertices in the closo-boranes corresp...
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The title compound, [Ag(2)(NCS)(2)(C(14)H(38)B(10)P(2))(2)], was synthesized by the reaction of 1,2-bis-(diiso-propyl-phos-phan-yl)-1,2-dicarba-closo-dodeca-borane with AgSCN. The diisopropyl-phosphanyl-closo-carborane ligand is coordinated in a bidentate manner to the Ag(I) atom through the two P atoms. The coordination of the Ag(I) atom is distorted tetra-hedral, in which two vertices are for...
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Pheromones are low molecular weight chemical substances that are produced by a plant or animal and cause a response in another individual of same or another spices. Pheromones can be of many different chemical types, to serve different functions even for survival of the individual. Pheromones are sending out subconscious scent signals to male or female that naturally trigger attraction, arousal...
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2017
ISSN: 2041-1723
DOI: 10.1038/ncomms15136